Cargando...
Conformationally Locked Pyramidality Explains the Diastereoselectivity in the Methylation of trans-Fused Butyrolactones
[Image: see text] A stereoselectivity model inspired by the total synthesis of stemona alkaloids is developed to explain why enolate-derived 3,4-fused butyrolactones are methylated with a preference for syn alkylation. The model shows how conformational locking present in nonplanar enolate structure...
Guardado en:
| Publicado en: | Org Lett |
|---|---|
| Autores principales: | , , , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
American
Chemical Society
2020
|
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7309317/ https://ncbi.nlm.nih.gov/pubmed/32338517 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.0c01008 |
| Etiquetas: |
Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
|