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Stretching the P–C Bond. Variations on Carbenes and Phosphanes

[Image: see text] The stability and the structure of adducts formed between four substituted phosphanes (PX(3), X:H, F, Cl, and NMe(2)) and 11 different carbenes have been investigated by DFT calculations. In most cases, the structure of the adducts depends strongly on the stability of the carbene i...

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Publicat a:J Phys Chem A
Autors principals: Buzsáki, Dániel, Kelemen, Zsolt, Nyulászi, László
Format: Artigo
Idioma:Inglês
Publicat: American Chemical Society 2020
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7307921/
https://ncbi.nlm.nih.gov/pubmed/32159965
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.jpca.0c00641
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