Site-Selective Orbital Interactions in an Ultrathin Iron-Carbene Photosensitizer Film

[Image: see text] We present the first experimental study of the frontier orbitals in an ultrathin film of the novel hexa-carbene photosensitizer [Fe(btz)(3)](3+), where btz is 3,3′-dimethyl-1,1′-bis(p-tolyl)-4,4′-bis(1,2,3-triazol-5-ylidene). Resonant photoelectron spectroscopy (RPES) was used to p...

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Udgivet i:J Phys Chem A
Main Authors: Temperton, Robert H., Rosemann, Nils W., Guo, Meiyuan, Johansson, Niclas, Fredin, Lisa A., Prakash, Om, Wärnmark, Kenneth, Handrup, Karsten, Uhlig, Jens, Schnadt, Joachim, Persson, Petter
Format: Artigo
Sprog:Inglês
Udgivet: American Chemical Society 2020
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7307919/
https://ncbi.nlm.nih.gov/pubmed/32011141
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.jpca.0c00803
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