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Performance of Electronic Structure Methods for the Description of Hückel–Möbius Interconversions in Extended π-Systems

[Image: see text] Expanded porphyrins provide a versatile route to molecular switching devices due to their ability to shift between several π-conjugation topologies encoding distinct properties. DFT remains the workhorse for modeling such extended macrocycles, when taking into account their size an...

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Detalhes bibliográficos
Publicado no:J Phys Chem A
Main Authors: Woller, Tatiana, Banerjee, Ambar, Sylvetsky, Nitai, Santra, Golokesh, Deraet, Xavier, De Proft, Frank, Martin, Jan M. L., Alonso, Mercedes
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2020
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7307915/
https://ncbi.nlm.nih.gov/pubmed/32093467
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.jpca.9b10880
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