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Self-Assembly of Multinuclear Sandwich Silver(I) Complexes by Cooperation of Hexakis(azaheteroaryl)benzene Ligands, Argentophilic Interactions, and Fluoride Inclusion

[Image: see text] Self-assembly of AgOTf and AgF with the hexatopic ligands hexakis(pyridin-2-yl)benzene (2) and 2,4,6-tris(pyridin-2-yl)-1,3,5-tris(quinolin-2-yl)benzene (3) affords the discrete sandwich-shaped complexes [Ag(4)F(2)(2)](OTf)(3), [Ag(4)F(3)(2)](OTf)(3), and [Ag(5)F(2)(2)](OTf)(4). Th...

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Detalhes bibliográficos
Publicado no:Inorg Chem
Main Authors: Drev, Miha, Grošelj, Uroš, Kočar, Drago, Perdih, Franc, Svete, Jurij, Štefane, Bogdan, Požgan, Franc
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2020
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7307899/
https://ncbi.nlm.nih.gov/pubmed/32133849
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.9b03664
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