Forcing Dicyanamide Coordination to f-Elements by Dissolution in Dicyanamide-Based Ionic Liquids

[Image: see text] A robust general route to lanthanide dicyanamide (DCA(–)) complexes has been developed where f-element salts are dissolved in DCA(–)-based ionic liquids (ILs) directly or formed in situ, forcing coordination of these normally weakly coordinating soft N-donor anions, even in an ambi...

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Detalhes bibliográficos
Publicado no:Inorg Chem
Main Authors: Tang, Si-Fu, Smetana, Volodymyr, Mishra, Manish Kumar, Kelley, Steven P., Renier, Olivier, Rogers, Robin D., Mudring, Anja-Verena
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2020
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7304860/
https://ncbi.nlm.nih.gov/pubmed/32364712
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.0c00667
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