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Tuning the Reactivity and Bonding Properties of Metal Square-Planar Complexes by the Substitution(s) on the Trans-Coordinated Pyridine Ring
[Image: see text] The kinetics of the hydration reaction on trans-[Pt(NH(3))(2)(pyrX)Cl](+) (pyr = pyridine) complexes (X = OH(–), Cl(–), F(–), Br(–), NO(2)(–), NH(2), SH(–), CH(3), C≡CH, and DMA) was studied by density functional theory calculations in the gas phase and in water solution described...
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| Publié dans: | ACS Omega |
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| Auteurs principaux: | , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
American Chemical Society
2020
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| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7254792/ https://ncbi.nlm.nih.gov/pubmed/32478268 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acsomega.0c01161 |
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