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A New Mechanism of Metal-Ligand Cooperative Catalysis in Transfer Hydrogenation of Ketones
We report iridium catalysts IrCl(η(5)-Cp*)(κ(2)-(2-pyridyl)CH(2)NSO(2)C(6)H(4)X) (1-Me, X = CH(3) and 1-F, X = F) for transfer hydrogenation of ketones with 2-propanol that operate by a previously unseen metal-ligand cooperative mechanism. Under the reaction conditions, complexes 1 (1-Me and 1-F) de...
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| Publicado no: | Polyhedron |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7224354/ https://ncbi.nlm.nih.gov/pubmed/32410767 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.poly.2020.114508 |
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