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Palladium-Catalysed Coupling Reactions En Route to Molecular Machines: Sterically Hindered Indenyl and Ferrocenyl Anthracenes and Triptycenes, and Biindenyls

Pd-catalysed Stille and Suzuki cross-couplings were used to prepare 9-(3-indenyl)-, 6, and 9-(2-indenyl)-anthracene, 7; addition of benzyne led to the 9-Indenyl-triptycenes, 8 and 9. In 6, [4 + 2] addition also occurred to the indenyl substituent. Reaction of 6 through 9 with Cr(CO)(6) or Re(2)(CO)(...

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Detalhes bibliográficos
Publicado no:Molecules
Main Authors: McGlinchey, Michael J., Nikitin, Kirill
Formato: Artigo
Idioma:Inglês
Publicado em: MDPI 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7222022/
https://ncbi.nlm.nih.gov/pubmed/32331469
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules25081950
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