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Improved Acid Resistance of a Metal–Organic Cage Enables Cargo Release and Exchange between Hosts

The use of di(2‐pyridyl)ketone in subcomponent self‐assembly is introduced. When combined with a flexible triamine and zinc bis(trifluoromethanesulfonyl)imide, this ketone formed a new Zn(4)L(4) tetrahedron 1 bearing twelve uncoordinated pyridyl units around its metal‐ion vertices. The acid stabilit...

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Publicat a:Angew Chem Int Ed Engl
Autors principals: Xu, Lin, Zhang, Dawei, Ronson, Tanya K., Nitschke, Jonathan R.
Format: Artigo
Idioma:Inglês
Publicat: John Wiley and Sons Inc. 2020
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7217015/
https://ncbi.nlm.nih.gov/pubmed/32073709
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202001059
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