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Silicon‐Free SuFEx Reactions of Sulfonimidoyl Fluorides: Scope, Enantioselectivity, and Mechanism

SuFEx reactions, in which an S−F moiety reacts with a silyl‐protected phenol, have been developed as powerful click reactions. In the current paper we open up the potential of SuFEx reactions as enantioselective reactions, analyze the role of Si and outline the mechanism of this reaction. As a resul...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Liang, Dong‐Dong, Streefkerk, Dieuwertje E., Jordaan, Daan, Wagemakers, Jorden, Baggerman, Jacob, Zuilhof, Han
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7216998/
https://ncbi.nlm.nih.gov/pubmed/32157791
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201915519
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