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Metal-Free Defluorinative Arylation of Trifluoromethyl Alkenes via Photoredox Catalysis

Literature methods to access gem-difluoroalkenes are largely limited to harsh, organometallic-based methods, and known photoredox mediated processes are not amenable to aryl radical addition to trifluoromethyl alkenes. A mild, metal-free, functional group-tolerant method for the preparation of benzy...

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Bibliografische gegevens
Gepubliceerd in:Chem Commun (Camb)
Hoofdauteurs: Wiles, Rebecca J., Phelan, James P., Molander, Gary A.
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: 2019
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Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7210470/
https://ncbi.nlm.nih.gov/pubmed/31199418
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9cc04265b
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