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Theoretical study on preference of open polymer vs. cyclic products in CO(2)/epoxide copolymerization with cobalt(III)-salen bifunctional catalysts

The preference of open chain of growing macromolecule vs. possible cyclic form was examined for the bifunctional cobalt(III)-salen catalyst for the copolymerization of CO(2) with epoxides. A variety of possible isomers was considered (resulting from trans/cis-β salen arrangement, different mutual or...

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Pubblicato in:J Mol Model
Autori principali: Roznowska, Aleksandra, Dyduch, Karol, Lee, Bun Yeoul, Michalak, Artur
Natura: Artigo
Lingua:Inglês
Pubblicazione: Springer Berlin Heidelberg 2020
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC7203596/
https://ncbi.nlm.nih.gov/pubmed/32378131
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1007/s00894-020-04364-x
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