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Asymmetric Synthesis of Homocitric Acid Lactone
A short, diastereoselective synthesis of homocitric acid lactone is described. The key step is a bioinspired aldol addition to set the stereogenic center in an intermediate that requires only modest oxidation state manipulation to complete the synthesis. This approach enables rapid generation of iso...
Gardado en:
| Publicado en: | J Org Chem |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2016
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7190193/ https://ncbi.nlm.nih.gov/pubmed/27685496 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.6b01997 |
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