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Asymmetric Synthesis of Homocitric Acid Lactone

A short, diastereoselective synthesis of homocitric acid lactone is described. The key step is a bioinspired aldol addition to set the stereogenic center in an intermediate that requires only modest oxidation state manipulation to complete the synthesis. This approach enables rapid generation of iso...

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Bibliografiske detaljer
Udgivet i:J Org Chem
Main Authors: Nickerson, Leslie A., Huynh, Valerie, Balmond, Edward I., Cramer, Stephen P., Shaw, Jared T.
Format: Artigo
Sprog:Inglês
Udgivet: 2016
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7190193/
https://ncbi.nlm.nih.gov/pubmed/27685496
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.6b01997
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