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One-pot synthesis of dicyclopenta-fused peropyrene via a fourfold alkyne annulation
A novel dicyclopenta-fused peropyrene derivative 1 was synthesized via a palladium-catalyzed four-fold alkyne annulation of 1,3,6,8-tetrabromo-2,7-diphenylpyrene (5) with diphenylacetylene. The annulative π-extension reaction toward 1 involved a twofold [3 + 2] cyclopentannulation and subsequent two...
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| Publicado en: | Beilstein J Org Chem |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
Beilstein-Institut
2020
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7188986/ https://ncbi.nlm.nih.gov/pubmed/32395182 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.16.72 |
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