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Effective and Reversible Carbon Dioxide Insertion into Cerium Pyrazolates
The homoleptic pyrazolate complexes [Ce(III) (4)(Me(2)pz)(12)] and [Ce(IV)(Me(2)pz)(4)](2) quantitatively insert CO(2) to give [Ce(III) (4)(Me(2)pz⋅CO(2))(12)] and [Ce(IV)(Me(2)pz⋅CO(2))(4)], respectively (Me(2)pz=3,5‐dimethylpyrazolato). This process is reversible for both complexes, as observed by...
Wedi'i Gadw mewn:
| Cyhoeddwyd yn: | Angew Chem Int Ed Engl |
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| Prif Awduron: | , , , |
| Fformat: | Artigo |
| Iaith: | Inglês |
| Cyhoeddwyd: |
John Wiley and Sons Inc.
2020
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| Pynciau: | |
| Mynediad Ar-lein: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7155069/ https://ncbi.nlm.nih.gov/pubmed/31916355 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201916483 |
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