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Synthesis and Reactivity of the First Isolated Hydrogen‐Bridged Silanol–Silanolate Anions

We report on the first examples of isolated silanol–silanolate anions, obtained by utilizing weakly coordinating phosphazenium counterions. The silanolate anions were synthesized from the recently published phosphazenium hydroxide hydrate salt with siloxanes. The silanol–silanolate anions are postul...

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Détails bibliographiques
Publié dans:Angew Chem Int Ed Engl
Auteurs principaux: Weitkamp, Robin F., Neumann, Beate, Stammler, Hans‐Georg, Hoge, Berthold
Format: Artigo
Langue:Inglês
Publié: John Wiley and Sons Inc. 2020
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Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC7154667/
https://ncbi.nlm.nih.gov/pubmed/31833629
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201914339
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