An Air‐Stable Heterobimetallic Si(2)M(2) Tetrahedral Cluster

Air‐ and moisture‐stable heterobimetallic tetrahedral clusters [Cp(CO)(2)MSiR](2) (M=Mo or W; R=SitBu(3)) were isolated from the reaction of N‐heterocyclic carbene (NHC) stabilized silyl(silylidene) metal complexes Cp(CO)(2)M=Si(SitBu(3))NHC with a mild Lewis acid (BPh(3)). Alternatively, treatment...

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Bibliographic Details
Published in:Angew Chem Int Ed Engl
Main Authors: Dübek, Gizem, Hanusch, Franziska, Munz, Dominik, Inoue, Shigeyoshi
Format: Artigo
Language:Inglês
Published: John Wiley and Sons Inc. 2020
Subjects:
Research Articles
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC7154520/
https://ncbi.nlm.nih.gov/pubmed/31943662
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201916116
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