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Sulfur-centered hemi-bond radicals as active intermediates in S-DNA phosphorothioate oxidation
Phosphorothioate (PS) modifications naturally appear in bacteria and archaea genome and are widely used as antisense strategy in gene therapy. But the chemical effects of PS introduction as a redox active site into DNA (S-DNA) is still poorly understood. Herein, we perform time-resolved spectroscopy...
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| Publicado no: | Nucleic Acids Res |
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| Main Authors: | , , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Oxford University Press
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7145531/ https://ncbi.nlm.nih.gov/pubmed/31724721 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1093/nar/gkz987 |
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