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Infrared spectroscopy of O(•−) and OH(−) in water clusters: evidence for fast interconversion between O(•−) and OH(•)OH(−)†

We present infrared multiple photon dissociation (IRMPD) spectra of (H(2)O)(n)O(•−) and (H(2)O)(n)OH(−) cluster ensembles for [Formula: see text] and 47 in the range of 2400–4000 cm(−1). Both hydrated ions exhibit the same spectral features, in good agreement with theoretical calculations. Decomposi...

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Detalhes bibliográficos
Publicado no:Phys Chem Chem Phys
Main Authors: Lengyel, Jozef, Ončák, Milan, Herburger, Andreas, van der Linde, Christian, Beyer, Martin K.
Formato: Artigo
Idioma:Inglês
Publicado em: 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7100789/
https://ncbi.nlm.nih.gov/pubmed/28891582
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7cp04577h
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