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Stability/Activity Tradeoffs in Thermus thermophilus HB27 Laccase()

We report the temperature dependence of the formal potential of type 1 copper (Cu(T1)) in Thermus thermophilus HB27 laccase. Employing [Ru(NH(3))(4)(bpy)](PF(6))(2) (0.505 vs. NHE) as the redox titrant, we found that the Cu(T1)(2+/+) potential decreased from approximately 480 to 420 mV (vs. NHE) as...

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Publicat a:J Biol Inorg Chem
Autors principals: Shin, Jieun, Gray, Harry B., Winkler, Jay R.
Format: Artigo
Idioma:Inglês
Publicat: 2020
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7085441/
https://ncbi.nlm.nih.gov/pubmed/31970489
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1007/s00775-020-01754-7
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