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Roaming Dynamics and Conformational Memory in Photolysis of Formic Acid at 193 nm Using Time-resolved Fourier-transform Infrared Emission Spectroscopy

In photodissociation of trans-formic acid (HCOOH) at 193 nm, we have observed two molecular channels of CO + H(2)O and CO(2) + H(2) by using 1 μs-resolved Fourier-transform infrared emission spectroscopy. With the aid of spectral simulation, the CO spectra are rotationally resolved for each vibratio...

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Detalhes bibliográficos
Publicado no:Sci Rep
Principais autores: Tso, Cheng-Jui, Kasai, Toshio, Lin, King-Chuen
Formato: Artigo
Idioma:Inglês
Publicado em: Nature Publishing Group UK 2020
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7075954/
https://ncbi.nlm.nih.gov/pubmed/32179782
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41598-020-61642-7
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