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Two-Carbon Ring Expansion of 1-indanones via Insertion of Ethylene into Carbon–Carbon Bonds
A rhodium-catalyzed direct insertion of ethylene into a relatively unstrained carbon–carbon bond in 1-indanones is reported, which provides a two-carbon ring expansion strategy for preparing seven-membered cyclic ketones. As many 1-indanones are commercially available and ethylene is inexpensive, th...
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| Pubblicato in: | J Am Chem Soc |
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| Autori principali: | , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2019
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7075334/ https://ncbi.nlm.nih.gov/pubmed/31389237 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b07445 |
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