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Incorporation of Cr(III) into a Keggin Polyoxometalate as a Chemical Strategy to Stabilize a Labile {Cr(III)O(4)} Tetrahedral Conformation and Promote Unattended Single-Ion Magnet Properties

[Image: see text] Polyoxometalates (POMs) provide rigid and highly symmetric coordination sites and can be used as a strategy for the stabilization of magnetic ions. Herein, we report a new member of the Keggin archetype, the Cr-centered Keggin anion [α-CrW(12)O(40)](5–) (CrW(12)), with the unusual...

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Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Cyhoeddwyd yn:J Am Chem Soc
Prif Awduron: Gumerova, Nadiia I., Roller, Alexander, Giester, Gerald, Krzystek, J., Cano, Joan, Rompel, Annette
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: American Chemical Society 2020
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC7052816/
https://ncbi.nlm.nih.gov/pubmed/31967803
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b12797
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