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Stereodivergent Photoelectrocyclization Reactions of Bis-aryl Cycloalkenones: Intercepting Photoelectrocyclization Intermediates with Acid
Described here are tandem photoelectrocyclization and [l,5]-hydride shift reactions of heteroaryl-containing bis-aryl cyclohexenone derivatives that give heteroaryl-substituted dihydrophenanthrenes. This Letter demonstrates that electrocyclization intermediates can be trapped with acid when the [l,5...
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| Pubblicato in: | Org Lett |
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| Autori principali: | , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2019
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7041411/ https://ncbi.nlm.nih.gov/pubmed/31621339 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.9b03214 |
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