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How do the Hückel and Baird Rules Fade away in Annulenes?

Two of the most popular rules to characterize the aromaticity of molecules are those due to Hückel and Baird, which govern the aromaticity of singlet and triplet states. In this work, we study how these rules fade away as the ring structure increases and an optimal overlap between p orbitals is no l...

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Detalhes bibliográficos
Publicado no:Molecules
Main Authors: Casademont-Reig, Irene, Ramos-Cordoba, Eloy, Torrent-Sucarrat, Miquel, Matito, Eduard
Formato: Artigo
Idioma:Inglês
Publicado em: MDPI 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7037833/
https://ncbi.nlm.nih.gov/pubmed/32045990
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules25030711
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