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Competition between Intra and Intermolecular Triel Bonds. Complexes between Naphthalene Derivatives and Neutral or Anionic Lewis Bases
A TrF(2) group (Tr = B, Al, Ga, In, Tl) is placed on one of the α positions of naphthalene, and its ability to engage in a triel bond (TrB) with a weak (NCH) and strong (NC(−)) nucleophile is assessed by ab initio calculations. As a competitor, an NH(2) group is placed on the neighboring C(α), from...
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| 發表在: | Molecules |
|---|---|
| Main Authors: | , , |
| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
MDPI
2020
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7037318/ https://ncbi.nlm.nih.gov/pubmed/32024163 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules25030635 |
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