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Cycloaddition Chemistry of a Silylene‐Nickel Complex toward Organic π‐Systems: From Reversibility to C−H Activation
The versatile cycloaddition chemistry of the Si−Ni multiple bond in the acyclic (amido)(chloro)silylene→Ni(0) complex 1, [((TMS)L)ClSi→Ni(NHC)(2)] ((TMS)L=N(SiMe(3))Dipp; Dipp=2,6‐iPr(2)C(6)H(4); NHC=C[(iPr)NC(Me)](2)), toward unsaturated organic substrates is reported, which is both reminiscent of...
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| Udgivet i: | Chemistry |
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| Main Authors: | , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
John Wiley and Sons Inc.
2020
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7028101/ https://ncbi.nlm.nih.gov/pubmed/31898825 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202000009 |
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