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Nickela‐electrocatalyzed C−H Alkoxylation with Secondary Alcohols: Oxidation‐Induced Reductive Elimination at Nickel(III)

Nickela‐electrooxidative C−H alkoxylations with challenging secondary alcohols were accomplished in a fully dehydrogenative fashion, thereby avoiding stoichiometric chemical oxidants, with H(2) as the only stoichiometric byproduct. The nickela‐electrocatalyzed oxygenation proved viable with various...

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Shranjeno v:
Bibliografske podrobnosti
izdano v:Angew Chem Int Ed Engl
Main Authors: Zhang, Shou‐Kun, Struwe, Julia, Hu, Lianrui, Ackermann, Lutz
Format: Artigo
Jezik:Inglês
Izdano: John Wiley and Sons Inc. 2020
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC7028089/
https://ncbi.nlm.nih.gov/pubmed/31729814
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201913930
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