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Unexpected Isomerization of Hexa‐tert‐butyl‐octaphosphane
Octaphosphane {cyclo‐(P(4) tBu(3))}(2) (1) undergoes an unexpected isomerization reaction to the constitutional isomer 2,2′,2′′,2′′′,3,3′‐hexa‐tert‐butyl‐bicyclo[3.3.0]octaphosphane (2) in the presence of Lewis acidic metal salts. The mechanism of this reaction is discussed and elucidated with DFT c...
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| Publicado no: | Chemistry |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7027762/ https://ncbi.nlm.nih.gov/pubmed/31758612 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201904531 |
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