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Reduction of Activated Alkenes by P(III)/P(V) Redox Cycling Catalysis
The carbon–carbon double bond of unsaturated carbonyl compounds was readily reduced by using a phosphetane oxide catalyst in the presence of a simple organosilane as the terminal reductant and water as the hydrogen source. Quantitative hydrogenation was observed when 1.0 mol % of a methyl‐substitute...
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| Pubblicato in: | Angew Chem Int Ed Engl |
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| Autori principali: | , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
John Wiley and Sons Inc.
2020
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7027467/ https://ncbi.nlm.nih.gov/pubmed/31793147 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201912991 |
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