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Divergent Catalytic Strategies for the Cis/Trans Stereoselective Ring-Opening Polymerization of a Dual Cyclic Carbonate/Olefin Monomer

[Image: see text] A dual seven-membered cyclic carbonate/olefin monomer was synthesized from CO(2) and cis-1,4-butenediol and polymerized. The properties of the polymer were controlled using divergent catalytic strategies toward the stereochemistry of the olefin. Ring-opening polymerization of the c...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: McGuire, Thomas M., Pérale, Cécile, Castaing, Rémi, Kociok-Köhn, Gabriele, Buchard, Antoine
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2019
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7007229/
https://ncbi.nlm.nih.gov/pubmed/31429566
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b06259
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