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Rich Polymorphism of a Metal–Organic Framework in Pressure–Temperature Space

[Image: see text] We present an in situ powder X-ray diffraction study on the phase stability and polymorphism of the metal–organic framework ZIF-4, Zn(imidazolate)(2), at simultaneous high pressure and high temperature, up to 8 GPa and 600 °C. The resulting pressure–temperature phase diagram reveal...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Widmer, Remo N., Lampronti, Giulio I., Chibani, Siwar, Wilson, Craig W., Anzellini, Simone, Farsang, Stefan, Kleppe, Annette K., Casati, Nicola P. M., MacLeod, Simon G., Redfern, Simon A. T., Coudert, François-Xavier, Bennett, Thomas D.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2019
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7007208/
https://ncbi.nlm.nih.gov/pubmed/31117654
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b03234
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