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Synthesis of bicyclo[3.1.0]hexanes by (3 + 2) annulation of cyclopropenes with aminocyclopropanes

We report the convergent synthesis of bicyclo[3.1.0]hexanes possessing an all-carbon quaternary center via a (3 + 2) annulation of cyclopropenes with cyclopropylanilines. Using an organic or an iridium photoredox catalyst and blue LED irradiation, good yields were obtained for a broad range of cyclo...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Muriel, Bastian, Gagnebin, Alec, Waser, Jerome
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7006509/
https://ncbi.nlm.nih.gov/pubmed/32110351
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc03790j
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