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Crystal structures and Hirshfeld surface analysis of trans-bis(thiocyanato-κN)bis{2,4,6-trimethyl-N-[(pyridin-2-yl)methylidene]aniline-κ(2) N,N′}manganese(II) and trans-bis(thiocyanato-κN)bis{2,4,6-trimethyl-N-[(pyridin-2-yl)methylidene]aniline-κ (2) N,N′}nickel(II))

Two new mononuclear metal complexes involving the bidentate Schiff base ligand 2,4,6-trimethyl-N-[(pyridin-2-yl)methylidene]aniline (C(15)H(16)N(2) or PM-TMA), [Mn(NCS)(2)(PM-TMA)(2)] (I) and [Ni(NCS)(2)(PM-TMA)(2)] (II), were synthesized and their structures determined by single-crystal X-ray diff...

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Bibliografske podrobnosti
izdano v:	Acta Crystallogr E Crystallogr Commun
Main Authors:	Jittirattanakun, Siripak, Theppitak, Chatphorn, Wannarit, Nanthawat, Rotsut, Bachari, Chainok, Kittipong
Format:	Artigo
Jezik:	Inglês
Izdano:	International Union of Crystallography 2020
Teme:	Research Communications
Online dostop:	https://ncbi.nlm.nih.gov/pmc/articles/PMC7001816/ https://ncbi.nlm.nih.gov/pubmed/32071764 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S2056989020000870
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Crystal structures and Hirshfeld surface analysis of trans-bis­(thio­cyanato-κN)bis­{2,4,6-trimethyl-N-[(pyridin-2-yl)methyl­idene]aniline-κ(2) N,N′}manganese(II) and trans-bis­(thio­cyanato-κN)bis­{2,4,6-trimethyl-N-[(pyridin-2-yl)methyl­idene]aniline-κ (2) N,N′}nickel(II))

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Crystal structures and Hirshfeld surface analysis of trans-bis(thiocyanato-κN)bis{2,4,6-trimethyl-N-[(pyridin-2-yl)methylidene]aniline-κ(2) N,N′}manganese(II) and trans-bis(thiocyanato-κN)bis{2,4,6-trimethyl-N-[(pyridin-2-yl)methylidene]aniline-κ (2) N,N′}nickel(II))