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Direct Carbon Isotope Exchange Through Decarboxylative Carboxylation
A two-step degradation-reconstruction approach to the carbon-14 radiolabeling of alkyl carboxylic acids is presented. Simple activation via redox-active ester formation was followed by nickel-mediated decarboxylative carboxylation to afford a range of complex compounds with ample isotopic incorporat...
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| Publicat a: | J Am Chem Soc |
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| Autors principals: | , , , , , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2019
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7000106/ https://ncbi.nlm.nih.gov/pubmed/30605319 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b12035 |
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