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Total synthesis of (-)-tubingensin B enabled by the strategic use of an aryne cyclization
Tubingensin B is an indole diterpenoid that bears a daunting chemical structure featuring a disubstituted carbazole unit, five stereogenic centres—three of which are quaternary—and a decorated [3.2.2]-bridged bicycle. We describe our synthetic design toward a concise and enantiospecific total synthe...
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| Publicado no: | Nat Chem |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6994261/ https://ncbi.nlm.nih.gov/pubmed/28937679 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/nchem.2801 |
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