Selective synthesis of formamides, 1,2-bis(N-heterocyclic)ethanes and methylamines from cyclic amines and CO(2)/H(2) catalyzed by an ionic liquid–Pd/C system

The reduction of CO(2) with amines and H(2) generally produces N-formylated or N-methylated compounds over different catalysts. Herein, we report the selective synthesis of formamides, 1,2-bis(N-heterocyclic)ethanes, and methylamines, which is achieved over an ionic liquid (IL, e.g., 1-butyl-3-methy...

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Gepubliceerd in:Chem Sci
Hoofdauteurs: Li, Ruipeng, Zhao, Yanfei, Wang, Huan, Xiang, Junfeng, Wu, Yunyan, Yu, Bo, Han, Buxing, Liu, Zhimin
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: Royal Society of Chemistry 2019
Onderwerpen:
Chemistry
Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6977556/
https://ncbi.nlm.nih.gov/pubmed/32015804
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc03242h
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