Manganese(I)‐Catalyzed β‐Methylation of Alcohols Using Methanol as C(1) Source

Highly selective β‐methylation of alcohols was achieved using an earth‐abundant first row transition metal in the air stable molecular manganese complex [Mn(CO)(2)Br[HN(C(2)H(4)P(i)Pr(2))(2)]] 1 ([HN(C(2)H(4)P(i)Pr(2))(2)]=MACHO‐(i)Pr). The reaction requires only low loadings of 1 (0.5 mol %), metha...

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Bibliografiska uppgifter
I publikationen:Angew Chem Int Ed Engl
Huvudupphovsmän: Kaithal, Akash, van Bonn, Pit, Hölscher, Markus, Leitner, Walter
Materialtyp: Artigo
Språk:Inglês
Publicerad: John Wiley and Sons Inc. 2019
Ämnen:
Communications
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC6973237/
https://ncbi.nlm.nih.gov/pubmed/31651071
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201909035
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