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Additions to N‐Sulfinylamines as an Approach for the Metal‐free Synthesis of Sulfonimidamides: O‐Benzotriazolyl Sulfonimidates as Activated Intermediates

Sulfonimidamides are obtained in moderate to very good yields from the key intermediates O‐benzotriazolyl sulfonimidates, which are formed by reacting aryldiazonium tetrafluoroborates, N‐tritylsulfinylamine, and N‐hydroxybenzotriazole hydrate in a process mediated by a tertiary amine. The formation...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Bremerich, Maximilian, Conrads, Christian M., Langletz, Tim, Bolm, Carsten
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6972565/
https://ncbi.nlm.nih.gov/pubmed/31609528
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201911075
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