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Quantification of energy of activation to supramolecular nanofibre formation reveals enthalpic and entropic effects and morphological consequence

We show a self-assembly process leading to fibres from a system that starts far from equilibrium because of fast solvent – anti-solvent mixing and analyse the activation energies associated with the aggregation. It is in some ways reminiscent of diverse natural fibrous materials that have kinetic be...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Samperi, Mario, Pérez-García, Lluïsa, Amabilino, David B.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6968731/
https://ncbi.nlm.nih.gov/pubmed/32015821
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc03280k
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