A hierarchically assembled 88-nuclei silver-thiacalix[4]arene nanocluster

Thiacalix[4]arenes as a family of promising ligands have been widely used to construct polynuclear metal clusters, but scarcely employed in silver nanoclusters. Herein, an anion-templated Ag(88) nanocluster (SD/Ag88a) built from p-tert-butylthiacalix[4]arene (H(4)TC4A) is reported. Single-crystal X-...

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Udgivet i:Nat Commun
Main Authors: Wang, Zhi, Su, Hai-Feng, Gong, Yi-Wen, Qu, Qing-Ping, Bi, Yan-Feng, Tung, Chen-Ho, Sun, Di, Zheng, Lan-Sun
Format: Artigo
Sprog:Inglês
Udgivet: Nature Publishing Group UK 2020
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Article
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6965622/
https://ncbi.nlm.nih.gov/pubmed/31949133
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-019-13682-5
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