Photodissociation transition states characterized by chirped pulse millimeter wave spectroscopy

The 193-nm photolysis of CH(2)CHCN illustrates the capability of chirped-pulse Fourier transform millimeter-wave spectroscopy to characterize transition states. We investigate the HCN, HNC photofragments in highly excited vibrational states using both frequency and intensity information. Measured re...

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Udgivet i:Proc Natl Acad Sci U S A
Main Authors: Prozument, Kirill, Baraban, Joshua H., Changala, P. Bryan, Park, G. Barratt, Shaver, Rachel G., Muenter, John S., Klippenstein, Stephen J., Chernyak, Vladimir Y., Field, Robert W.
Format: Artigo
Sprog:Inglês
Udgivet: National Academy of Sciences 2020
Fag:
Physical Sciences
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6955290/
https://ncbi.nlm.nih.gov/pubmed/31852828
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1911326116
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