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Strong inverse kinetic isotope effect observed in ammonia charge exchange reactions

Isotopic substitution has long been used to understand the detailed mechanisms of chemical reactions; normally the substitution of hydrogen by deuterium leads to a slower reaction. Here, we report our findings on the charge transfer collisions of cold [Formula: see text] ions and two isotopologues o...

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Detalhes bibliográficos
Publicado no:Nat Commun
Main Authors: Petralia, L. S., Tsikritea, A., Loreau, J., Softley, T. P., Heazlewood, B. R.
Formato: Artigo
Idioma:Inglês
Publicado em: Nature Publishing Group UK 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6954264/
https://ncbi.nlm.nih.gov/pubmed/31924778
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-019-13976-8
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