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Intramolecular Hydrogen Bonds in Normal and Sterically Compressed o-Hydroxy Aromatic Aldehydes. Isotope Effects on Chemical Shifts and Hydrogen Bond Strength

A number of o-hydroxy aromatic aldehydes have been synthesized to illustrate the effect of steric compression and O···O distances on the intramolecular hydrogen bond and the hydrogen bond energies. Hydrogen bond energies have been calculated using the ‘hb and out’ method using either the MP2 method...

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Опубликовано в: :Molecules
Главные авторы: Hansen, Poul Erik, Kamounah, Fadhil S., Saeed, Bahjat A., MacLachlan, Mark J., Spanget-Larsen, Jens
Формат: Artigo
Язык:Inglês
Опубликовано: MDPI 2019
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Online-ссылка:https://ncbi.nlm.nih.gov/pmc/articles/PMC6943505/
https://ncbi.nlm.nih.gov/pubmed/31835750
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules24244533
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