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A One-pot, Three-Aryne Cascade Strategy for Naphthalene Formation from 1,3-Diynes and 1,2-Benzdiyne Equivalents
Here we disclose a cascade strategy for naphthyne formation that capitalizes on the traditional benzyne generation (i.e., from an ortho-silyl aryl triflate) and the thermal hexadehydro-Diels–Alder (HDDA) reaction. In this transformation, three distinct aryne species work in tandem, two of which can...
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| Udgivet i: | J Am Chem Soc |
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| Main Authors: | , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2019
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6933537/ https://ncbi.nlm.nih.gov/pubmed/31181885 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b04606 |
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