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Strategies for Enhancing the Rate Constant of C–H Bond Cleavage by Concerted Proton-Coupled Electron Transfer
Recently the selective C–H bond cleavage under mild conditions with weak oxidants was reported for fluorenyl-benzoates. This mechanism is based on multi-site concerted proton-coupled electron transfer (PCET) involving intermolecular electron transfer to an outer-sphere oxidant coupled to intramolecu...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6927470/ https://ncbi.nlm.nih.gov/pubmed/31464122 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b06849 |
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