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Exploiting Imine Photochemistry for Masked N-Centered Radical Reactivity

This report details the development of a masked N-centered radical strategy that harvests the energy of light to drive the conversion of cyclopropylimines to 1-aminonorbornanes. This process employs the N-centered radical character of a photoexcited imine to facilitate the homolytic fragmentation of...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Staveness, Daryl, Collins, James L., McAtee, Rory C., Stephenson, Corey R.J.
Formato: Artigo
Idioma:Inglês
Publicado em: 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6917850/
https://ncbi.nlm.nih.gov/pubmed/31701606
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201909492
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