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Old Concepts, New Application – Additive‐Free Hydrogenation of Nitriles Catalyzed by an Air Stable Alkyl Mn(I) Complex
An efficient additive‐free manganese‐catalyzed hydrogenation of nitriles to primary amines with molecular hydrogen is described. The pre‐catalyst, a well‐defined bench‐stable alkyl bisphosphine Mn(I) complex fac‐[Mn(dpre)(CO)(3)(CH(3))] (dpre=1,2‐bis(di‐n‐propylphosphino)ethane), undergoes CO migrat...
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| Udgivet i: | Adv Synth Catal |
|---|---|
| Main Authors: | , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
John Wiley and Sons Inc.
2019
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6916632/ https://ncbi.nlm.nih.gov/pubmed/31875866 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/adsc.201901040 |
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