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Charging OBO‐Fused Double [5]Helicene with Electrons

Chemical reduction of OBO‐fused double[5]helicene with Group 1 metals (Na and K) has been investigated for the first time. Two doubly‐reduced products have been isolated and structurally characterized by single‐crystal X‐ray diffraction, revealing a solvent‐separated ion triplet (SSIT) with Na(+) io...

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Bibliografiske detaljer
Udgivet i:Angew Chem Int Ed Engl
Main Authors: Zhou, Zheng, Wang, Xiao‐Ye, Wei, Zheng, Müllen, Klaus, Petrukhina, Marina A.
Format: Artigo
Sprog:Inglês
Udgivet: John Wiley and Sons Inc. 2019
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6916263/
https://ncbi.nlm.nih.gov/pubmed/31430019
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201908658
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